| 1.1 | Jolene | Dolly Parton, Hurshel Wiginton, Joe Babcock, Dolores Edgin, June Page | 2:39 |
| 1.2 | Stand by Your Man | Tammy Wynette | 2:42 |
| 1.3 | The Most Beautiful Girl | Charlie Rich | 2:42 |
| 1.4 | The Devil Went Down to Georgia | Charlie Daniels, Tom Crain | 3:36 |
| 1.5 | Folsom Prison Blues | Johnny Cash | 2:46 |
| 1.6 | Snowbird | Elvis Presley | 2:05 |
| 1.7 | Always on My Mind | Willie Nelson | 3:32 |
| 1.8 | Me and Bobby McGee | Janis Joplin, Richard Bell, Brad Campbell, Clark Pierson, Ken Pearson, John Till, Vince Mitchell, Phil Badella, John Cooke | 4:28 |
| 1.9 | Why Me | Kris Kristofferson | 3:28 |
| 1.10 | Sylvia’s Mother | Dr. Hook & the Medicine Show | 3:51 |
| 1.11 | Highwayman | Johnny Cash, Paul Davis, Waylon Jennings, Kris Kristofferson, Willie Nelson, Johnny Rodriguez, Chips Moman | 3:04 |
| 1.12 | Seven Year Ache | Rosanne Cash | 3:18 |
| 1.13 | I’ve Been Loved by the Best | Don Williams | 3:34 |
| 1.14 | That’s the Way Love Goes | Merle Haggard | 3:02 |
| 1.15 | A Rusty Old Halo | Hoyt Axton | 2:36 |
| 1.16 | Take This Job and Shove It | Johnny Paycheck | 2:38 |
| 1.17 | Sea of Heartbreak | Don Gibson | 2:33 |
| 1.18 | El Paso | Marty Robbins | 4:21 |
| 1.19 | Big Bad John | Jimmy Dean | 3:02 |
| 1.20 | He’ll Have to Go | Jim Reeves | 2:19 |
| 2.1 | Ring of Fire | Johnny Cash | 2:37 |
| 2.2 | On the Road Again | Willie Nelson | 2:25 |
| 2.3 | I Can Help | Billy Swan | 2:58 |
| 2.4 | Rose Garden | Lynn Anderson | 2:54 |
| 2.5 | Uneasy Rider | The Charlie Daniels Band | 5:19 |
| 2.6 | My Baby Thinks He’s a Train | Emmylou Harris, Rosemary Butler | 3:14 |
| 2.7 | Good Hearted Woman | Waylon Jennings | 3:00 |
| 2.8 | Tonight My Baby’s Coming Home | Barbara Mandrell | 2:05 |
| 2.9 | Kiss an Angel Good Mornin‘ | Charley Pride | 2:02 |
| 2.10 | Let’s Chase Each Other Around the Room | Merle Haggard | 2:51 |
| 2.11 | Little Black Book | Jimmy Dean | 2:26 |
| 2.12 | Delaware | Perry Como | 2:22 |
| 2.13 | Ringo | Lorne Greene | 3:14 |
| 2.14 | 500 Miles Away From Home | Bobby Bare | 2:44 |
| 2.15 | Please Help Me, I’m Falling | Hank Locklin | 2:22 |
| 2.16 | For the Good Times | Ray Price | 3:48 |
| 2.17 | He Stopped Loving Her Today | George Jones, [unknown] | 3:17 |
| 2.18 | Visions of Johanna | Marianne Faithfull | 4:35 |
| 2.19 | Would You Lay With Me (In a Field of Stone) | Tanya Tucker | 2:22 |
| 2.20 | Annie’s Song | John Denver | 3:01 |
| 3.1 | Islands in the Stream | Kenny Rogers, Dolly Parton | 4:09 |
| 3.2 | Sunday Mornin’ Comin’ Down | Kris Kristofferson | 4:32 |
| 3.3 | D-I-V-O-R-C-E | Tammy Wynette | 2:57 |
| 3.4 | Take Me Home, Country Roads | John Denver | 3:12 |
| 3.5 | The Gambler | Bobby Bare | 3:34 |
| 3.6 | Mammas Don’t Let Your Babies Grow Up to Be Cowboys | Waylon Jennings, Willie Nelson, Barny Robertson, Rance Wasson, Gordon Payne, Carter Robertson, Becky Williams | 2:32 |
| 3.7 | Whatever Happened to Old Fashioned Love | B.J. Thomas | 3:27 |
| 3.8 | Della and the Dealer | Hoyt Axton | 3:24 |
| 3.9 | Abilene | George Hamilton IV | 2:13 |
| 3.10 | Flowers on the Wall | The Statler Brothers | 2:20 |
| 3.11 | Yakety Axe | Chet Atkins | 2:03 |
| 3.12 | Oh Lonesome Me | Don Gibson | 2:30 |
| 3.13 | Desperados Waiting for a Train | The Highwaymen | 4:37 |
| 3.14 | Life Turned Her That Way | Ricky Van Shelton | 3:21 |
| 3.15 | One Good Well | Don Williams | 2:54 |
| 3.16 | Behind Closed Doors | Charlie Rich, The Nashville Edition | 2:55 |
| 3.17 | The Grand Tour | George Jones, The Jordanaires | 3:06 |
| 3.18 | Devil Woman | Marty Robbins | 2:52 |
| 3.19 | Distant Drums | Jim Reeves | 2:53 |
| 3.20 | The End of the World | Skeeter Davis | 2:35 |
| 4.1 | Lullaby | Shawn Mullins | 4:33 |
| 4.2 | Amazed | Lonestar | 4:01 |
| 4.3 | Guilty Flowers | Ward Thomas | 3:05 |
| 4.4 | Born to Fly | Sara Evans | 5:36 |
| 4.5 | You | Wes Hightower | 2:46 |
| 4.6 | Angel Eyes | Love and Theft | 3:07 |
| 4.7 | If You Ever Stop Loving Me | Montgomery Gentry | 3:24 |
| 4.8 | Just Another Day in Paradise | Phil Vassar | 3:55 |
| 4.9 | It’s Five O’ Clock Somewhere | Alan Jackson, Jimmy Buffett, John Wesley Ryles | 3:51 |
| 4.10 | Smoky Mountain Rain | Ronnie Milsap | 3:43 |
| 4.11 | My Maria | Brooks & Dunn | 3:30 |
| 4.12 | Wild Angels | Martina McBride | 3:45 |
| 4.13 | Pickup Man | Joe Diffie | 3:37 |
| 4.14 | I Feel Lucky | Mary Chapin Carpenter | 3:32 |
| 4.15 | Next to You, Next to Me | Shenandoah | 3:39 |
| 4.16 | Woke Up in Love | Exile | 3:06 |
| 4.17 | Love in the First Degree | Alabama | 3:17 |
| 4.18 | I’ll Leave This World Loving You | Ricky Van Shelton | 3:07 |
| 4.19 | Here I Am | Patty Loveless | 3:05 |
| 4.20 | Best of Intentions | Travis Tritt | 4:17 |
| 5.1 | Sleepwalking | Lissie | 4:14 |
| 5.2 | Carry You Home | Ward Thomas | 3:36 |
| 5.3 | Hold On | Wildwood Kin | 4:09 |
| 5.4 | Milk & Honey | Billie Marten | 3:58 |
| 5.5 | Redneck Woman | Gretchen Wilson | 3:38 |
| 5.6 | My Front Porch Looking | Lonestar | 3:44 |
| 5.7 | Barefoot Blue Jean Night | Wes Hightower | 2:48 |
| 5.8 | Crazy ’Bout You Baby | Billy Ray Cyrus | 3:21 |
| 5.9 | I Love You | Martina McBride | 2:53 |
| 5.10 | You Can Feel Bad | Patty Loveless | 3:25 |
| 5.11 | There Ain’t Nothin’ Wrong With the Radio | Aaron Tippin | 2:47 |
| 5.12 | Chattahoochee | Alan Jackson | 2:29 |
| 5.13 | Passionate Kisses | Shawn Colvin, Mary Chapin Carpenter | 3:22 |
| 5.14 | Mountain Music | Alabama | 3:39 |
| 5.15 | Hell on Heels | Pistol Annies | 3:15 |
| 5.16 | Ain’t Nothing ’Bout You | Brooks & Dunn | 3:21 |
| 5.17 | It’s a Great Day to Be Alive | Travis Tritt | 4:03 |
| 5.18 | She’s Everything | Brad Paisley | 4:27 |
| 5.19 | Roll With Me | Montgomery Gentry | 3:55 |
| 5.20 | Tomorrow | Chris Young | 3:40 |