| 1 | Ain’t No Mountain High Enough (mono version) | Marvin Gaye | 2:33 |
| 2 | My Girl (single version) | The Temptations | 2:56 |
| 3 | I Want You Back | Michael Jackson, Jermaine Jackson, Keith Washington, Jackie Jackson, Tito Jackson, Marlon Jackson | 2:53 |
| 4 | I’d Rather Go Blind | Etta James | 2:37 |
| 5 | Superstition | Stevie Wonder | 4:10 |
| 6 | I Can’t Help Myself (Sugar Pie, Honey Bunch) (single version / mono) | Four Tops | 2:45 |
| 7 | You Can’t Hurry Love (2003 remix) | The Supremes | 2:59 |
| 8 | I’m Coming Out | Diana Ross | 3:56 |
| 9 | I Heard It Through the Grapevine (single version) | Marvin Gaye, The Andantes, Louvain Demps, Jackie Hicks, Marlene Barrow | 3:12 |
| 10 | At Last | Etta James | 3:03 |
| 11 | Signed, Sealed, Delivered (I’m Yours) (single version / mono) | Stevie Wonder | 2:40 |
| 12 | ABC | The Jacksons | 3:11 |
| 13 | My Guy (“16 Big Hits” version) | Mary Wells | 2:50 |
| 14 | Brick House (single version) | Commodores | 3:37 |
| 15 | What’s Going On | Marvin Gaye, Mel Farr, Lem Barney | 3:53 |
| 16 | Please Mr. Postman | The Marvelettes | 2:31 |
| 17 | Give It to Me Baby (single version) | Rick James | 3:53 |
| 18 | Ooo Baby Baby (single version / mono) | The Miracles | 2:44 |
| 19 | For Once in My Life | Stevie Wonder | 2:47 |
| 20 | Baby Love (2003 remix) | The Supremes | 2:50 |
| 21 | Baby I Need Your Loving (2003 stereo mix) | Four Tops | 2:50 |
| 22 | Sir Duke | Stevie Wonder | 3:53 |
| 23 | Truly | Lionel Richie | 3:21 |
| 24 | Got to Be There (single version) | Michael Jackson | 3:23 |
| 25 | Stop! In the Name of Love (Juke Box single) | Diana Ross, Florence Ballard, Mary Wilson, The Andantes | 2:51 |
| 26 | Mercy Mercy Me (The Ecology) | Marvin Gaye, The Andantes | 3:16 |
| 27 | Three Times a Lady | Commodores | 6:38 |
| 28 | Nowhere to Run | Martha Reeves and the Vandellas | 3:00 |
| 29 | You Are the Sunshine of My Life | Stevie Wonder, Jim Gilstrap, Gloria Barley, Lani Groves | 2:57 |
| 30 | You’ve Really Got a Hold on Me | The Miracles | 2:53 |
| 31 | Got to Give It Up (Pt. 1) | Marvin Gaye | 4:08 |
| 32 | I’ll Be There (edit) | The Jacksons | 3:42 |
| 33 | Being With You (single version) | Smokey Robinson | 4:07 |
| 34 | The Way You Do the Things You Do | Eddie Kendricks, David Ruffin, Otis Williams, Paul Williams, Melvin Franklin | 2:42 |
| 35 | Papa’s Got a Brand New Bag (Pt. 1) | James Brown | 2:06 |
| 36 | It’s the Same Old Song | Lawrence Payton, Levi Stubbs, Renaldo Benson, Abdul “Duke” Fakir, Louvain Demps, Jackie Hicks, Marlene Barrow | 2:47 |
| 37 | Where Did Our Love Go (2003 remix) | Diana Ross, Florence Ballard, Mary Wilson | 2:41 |
| 38 | Respect Yourself | The Staple Singers | 3:31 |
| 39 | Someday We’ll Be Together | Diana Ross, Johnny Bristol, Merry Clayton, Julia Waters, Maxine Waters | 3:26 |
| 40 | Touch Me in the Morning | Diana Ross | 3:53 |
| 41 | You’re All I Need to Get By | Tammi Terrell | 2:48 |
| 42 | I Wish It Would Rain | The Temptations | 2:50 |
| 43 | River Deep – Mountain High | Tina Turner | 3:36 |
| 44 | Higher Ground | Stevie Wonder | 3:43 |
| 45 | You Beat Me to the Punch | Mary Wells | 2:45 |
| 46 | The Love You Save | Michael Jackson, Jermaine Jackson, Jackie Jackson, Tito Jackson, Marlon Jackson | 2:59 |
| 47 | Come See About Me | Diana Ross, Florence Ballard, Mary Wilson | 2:36 |
| 48 | Still (single version) | Commodores | 3:43 |
| 49 | Bernadette | Four Tops | 3:02 |
| 50 | My World Is Empty Without You | The Supremes | 2:34 |
| 51 | Since I Lost My Baby | David Ruffin | 2:55 |
| 52 | My Whole World Ended (The Moment You Left Me) | David Ruffin | 3:27 |
| 53 | Let’s Get It On | Marvin Gaye | 4:55 |
| 54 | Love Child (single version / mono) | The Andantes | 3:02 |
| 55 | Reach Out and Touch (Somebody’s Hand) | Diana Ross | 3:00 |