| 1.1 | Money (That's What I Want) (single version / mono) | Barrett Strong | 2:37 |
| 1.2 | Shop Around | The Miracles | 2:45 |
| 1.3 | Bye Bye Baby (single version / mono) | Mary Wells | 2:53 |
| 1.4 | Please Mr. Postman (single version / mono) | The Marvelettes | 2:29 |
| 1.5 | Do You Love Me | The Contours | 2:53 |
| 1.6 | You Beat Me to the Punch | Mary Wells | 2:51 |
| 1.7 | Stubborn Kind of Fellow | Marvin Gaye | 2:44 |
| 1.8 | Two Lovers | Mary Wells | 2:48 |
| 1.9 | You've Really Got a Hold on Me | The Miracles | 2:56 |
| 1.10 | Come and Get These Memories | Martha Reeves & The Vandellas | 2:28 |
| 1.11 | Pride and Joy | Marvin Gaye | 2:05 |
| 1.12 | Fingertips, Pt. 2 (live/1962) | Stevie Wonder | 3:10 |
| 1.13 | (Love Is Like a) Heat Wave | Martha Reeves & The Vandellas | 3:45 |
| 1.14 | Can I Get a Witness | Marvin Gaye | 2:46 |
| 1.15 | The Way You Do the Things You Do | The Temptations | 2:39 |
| 1.16 | My Guy | Mary Wells | 2:52 |
| 1.17 | Every Little Bit Hurts | Brenda Holloway | 2:55 |
| 1.18 | Where Did Our Love Go | The Supremes | 2:33 |
| 1.19 | Baby I Need Your Loving | Four Tops | 2:46 |
| 1.20 | Dancing in the Street | Martha Reeves & The Vandellas | 2:38 |
| 1.21 | Baby Love | The Supremes | 2:37 |
| 1.22 | How Sweet It Is (To Be Loved by You) | Marvin Gaye | 2:58 |
| 1.23 | Come See About Me | The Supremes | 2:41 |
| 1.24 | My Girl | The Temptations | 2:56 |
| 1.25 | He Was Really Sayin' Somethin' | The Velvelettes | 2:29 |
| 2.1 | Shotgun | Jr. Walker & The All Stars | 3:19 |
| 2.2 | Nowhere to Run | Martha Reeves & The Vandellas | 2:55 |
| 2.3 | Stop! In the Name of Love (single version) | The Supremes | 2:55 |
| 2.4 | Ooo Baby Baby | Smokey Robinson & The Miracles | 2:44 |
| 2.5 | I Can't Help Myself (Second version) | Four Tops | 2:45 |
| 2.6 | The Tracks of My Tears | Smokey Robinson & The Miracles | 2:54 |
| 2.7 | It's the Same Old Song | Four Tops | 2:46 |
| 2.8 | Ain't That Peculiar (single version) | Marvin Gaye | 3:01 |
| 2.9 | I Hear a Symphony | The Supremes | 2:43 |
| 2.10 | Uptight (Everything's Alright) (single version) | Stevie Wonder | 2:53 |
| 2.11 | Going to a Go-Go | Smokey Robinson & The Miracles | 2:45 |
| 2.12 | Don't Mess With Bill (single version) | The Marvelettes | 2:51 |
| 2.13 | My World Is Empty Without You | The Supremes | 2:34 |
| 2.14 | Get Ready | The Temptations | 2:35 |
| 2.15 | This Old Heart of Mine (Is Weak for You) | The Isley Brothers | 2:46 |
| 2.16 | (I'm a) Road Runner | Jr. Walker & The All Stars | 2:48 |
| 2.17 | Function at the Junction (single version) | Shorty Long | 2:54 |
| 2.18 | Ain't Too Proud to Beg | The Temptations | 2:34 |
| 2.19 | What Becomes of the Brokenhearted | Jimmy Ruffin | 2:58 |
| 2.20 | You Can't Hurry Love | The Supremes | 2:58 |
| 2.21 | Reach Out I'll Be There | Four Tops | 2:59 |
| 2.22 | Heaven Must Have Sent You | The Elgins | 2:34 |
| 2.23 | You Keep Me Hangin' On | The Supremes | 2:45 |
| 2.24 | (I Know) I'm Losing You | The Temptations | 2:26 |
| 2.25 | It Takes Two | Marvin Gaye & Kim Weston | 2:56 |
| 3.1 | Standing in the Shadows of Love | Four Tops | 2:38 |
| 3.2 | The Hunter Gets Captured by the Game | The Marvelettes | 2:50 |
| 3.3 | Jimmy Mack | Martha Reeves & The Vandellas | 3:08 |
| 3.4 | Bernadette | Four Tops | 3:09 |
| 3.5 | Ain't No Mountain High Enough | Marvin Gaye & Tammi Terrell | 2:27 |
| 3.6 | I Was Made to Love Her | Stevie Wonder | 2:40 |
| 3.7 | Your Precious Love | Marvin Gaye & Tammi Terrell | 2:59 |
| 3.8 | I Heard It Through the Grapevine | Gladys Knight & The Pips | 2:46 |
| 3.9 | If This World Were Mine | Marvin Gaye & Tammi Terrell | 2:40 |
| 3.10 | I Wish It Would Rain | The Temptations | 2:51 |
| 3.11 | I Second That Emotion | Smokey Robinson & The Miracles | 2:41 |
| 3.12 | Ain't Nothing Like the Real Thing | Marvin Gaye & Tammi Terrell | 2:16 |
| 3.13 | Does Your Mama Know About Me | Bobby Taylor & the Vancouvers | 2:51 |
| 3.14 | You're All I Need to Get By | Marvin Gaye & Tammi Terrell | 2:50 |
| 3.15 | Love Child | Diana Ross & The Supremes | 2:59 |
| 3.16 | For Once in My Life | Stevie Wonder | 2:51 |
| 3.17 | Cloud Nine | The Temptations | 3:29 |
| 3.18 | I'm Gonna Make You Love Me | Diana Ross & The Supremes & THE TEMPTATIONS | 3:06 |
| 3.19 | I Heard It Through the Grapevine | Marvin Gaye | 3:14 |
| 3.20 | Twenty Five Miles | Edwin Starr | 3:21 |
| 3.21 | My Whole World Ended (The Moment You Left Me) | David Ruffin | 3:26 |
| 3.22 | My Cherie Amour | Stevie Wonder | 2:55 |
| 3.23 | What Does It Take (To Win Your Love) | Jr. Walker & The All Stars | 2:30 |
| 3.24 | I Can't Get Next to You | The Temptations | 2:52 |
| 3.25 | Someday We'll Be Together (2003 remix) | Diana Ross & The Supremes | 3:31 |
| 4.1 | I Want You Back | Michael Jackson, Jermaine Jackson, Keith Washington, Jackie Jackson, Tito Jackson, Marlon Jackson | 2:58 |
| 4.2 | Up the Ladder to the Roof | The Supremes | 3:10 |
| 4.3 | ABC | The Jackson 5 | 3:08 |
| 4.4 | Reach Out and Touch (Somebody's Hand) | Diana Ross | 3:04 |
| 4.5 | Ball of Confusion (That's What the World Is Today) | The Temptations | 4:06 |
| 4.6 | The Love You Save | Michael Jackson, Jermaine Jackson, Jackie Jackson, Tito Jackson, Marlon Jackson | 3:04 |
| 4.7 | Signed, Sealed, Delivered (I'm Yours) | Stevie Wonder | 2:40 |
| 4.8 | War | Edwin Starr | 3:22 |
| 4.9 | It's a Shame | The Spinners | 3:14 |
| 4.10 | Ain't No Mountain High Enough | Diana Ross | 3:40 |
| 4.11 | Still Water (Love) | Four Tops | 3:11 |
| 4.12 | I'll Be There | The Jackson 5 | 3:57 |
| 4.13 | The Tears of a Clown | Smokey Robinson & The Miracles | 2:56 |
| 4.14 | If I Were Your Woman | Gladys Knight & The Pips | 3:12 |
| 4.15 | Just My Imagination (Running Away with Me) | The Temptations | 3:51 |
| 4.16 | What's Going On | Marvin Gaye | 3:58 |
| 4.17 | Never Can Say Goodbye | The Jackson 5 | 3:00 |
| 4.18 | Smiling Faces Sometimes | The Undisputed Truth | 3:16 |
| 4.19 | Mercy Mercy Me (The Ecology) | Marvin Gaye | 3:13 |
| 4.20 | I Just Want to Celebrate | Rare Earth | 3:36 |
| 4.21 | Got to Be There | Michael Jackson | 3:23 |
| 4.22 | Papa Was a Rollin' Stone | The Temptations | 6:59 |
| 4.23 | Let's Get It On | Marvin Gaye | 4:53 |
| 4.24 | Dancing Machine | The Jackson 5 | 2:36 |
| 4.25 | Neither One of Us (Wants to Be the First to Say Goodbye) | Gladys Knight & The Pips | 4:20 |