| 1.1 | When the Lovelight Starts Shining Through His Eyes | Diana Ross & The Supremes | 2:38 |
| 1.2 | Where Did Our Love Go | Diana Ross, Florence Ballard, Mary Wilson | 2:32 |
| 1.3 | Ask Any Girl | The Supremes | 2:42 |
| 1.4 | Baby Love ("16 Big Hits" version) | Diana Ross, Florence Ballard, Mary Wilson | 2:35 |
| 1.5 | Run, Run, Run (single version / mono) | The Supremes | 2:21 |
| 1.6 | Stop! In the Name of Love (single version / mono) | The Supremes | 2:52 |
| 1.7 | Back in My Arms Again (single version) | Diana Ross | 2:53 |
| 1.8 | Come See About Me | Diana Ross, Florence Ballard, Mary Wilson | 2:40 |
| 1.9 | Nothing but Heartaches (Juke Box single) | The Supremes | 2:56 |
| 1.10 | Everything Is Good About You (stereo version) | The Supremes | 3:06 |
| 1.11 | I Hear a Symphony (stereo version) | The Supremes | 2:38 |
| 1.12 | Love Is Here and Now You're Gone | The Supremes | 2:46 |
| 1.13 | My World Is Empty Without You | The Supremes | 2:33 |
| 1.14 | Whisper You Love Me Boy | Diana Ross & The Supremes | 2:40 |
| 1.15 | The Happening | Diana Ross, Florence Ballard, Mary Wilson | 2:50 |
| 1.16 | You Keep Me Hangin' On | The Supremes | 2:41 |
| 1.17 | You Can't Hurry Love | Diana Ross, Florence Ballard, Mary Wilson | 2:45 |
| 1.18 | Standing at the Crossroads of Love (single version) | Diana Ross & The Supremes | 2:28 |
| 1.19 | Love Is Like an Itching in My Heart | The Supremes | 2:55 |
| 1.20 | There's No Stopping Us Now (mono version) | The Supremes | 2:57 |
| 2.1 | Reflections | Diana Ross & The Supremes | 2:51 |
| 2.2 | Someday We'll Be Together | Diana Ross, Johnny Bristol, Merry Clayton, Julia Waters, Maxine Waters | 3:31 |
| 2.3 | Love Child | The Andantes | 2:55 |
| 2.4 | Some Things You Never Get Used To (single version) | The Andantes | 2:23 |
| 2.5 | Forever Came Today (single version) | Diana Ross & The Supremes | 3:13 |
| 2.6 | In and Out of Love (single version) | Diana Ross & The Supremes | 2:39 |
| 2.7 | I'm Livin' in Shame (Juke Box single) | The Andantes | 2:59 |
| 2.8 | No Matter What Sign You Are | The Andantes | 2:51 |
| 2.9 | The Composer (single version / mono) | Diana Ross & The Supremes | 2:59 |
| 2.10 | I'm Gonna Make You Love Me (stereo) | Diana Ross, Eddie Kendricks, Otis Williams | 3:07 |
| 2.11 | Stoned Love (single version) | Jean Terrell | 2:58 |
| 2.12 | I'm Gonna Let My Heart Do the Walking | Scherrie Payne | 3:08 |
| 2.13 | Floy Joy (single version) | Mary Wilson, Jean Terrell | 2:31 |
| 2.14 | Nathan Jones (single version) | Jean Terrell | 3:01 |
| 2.15 | The Sha-La Bandit | Cindy Birdsong, Scherrie Payne | 3:17 |
| 2.16 | Up the Ladder to the Roof (single version) | Mary Wilson, Cindy Birdsong, Jean Terrell | 3:14 |
| 2.17 | You're My Driving Wheel (single version) | Scherrie Payne | 3:19 |
| 2.18 | Everybody's Got the Right to Love | Jean Terrell | 2:38 |
| 2.19 | Bad Weather (single version) | Jean Terrell | 3:01 |
| 2.20 | Love Train | The Supremes | 3:20 |