| 22.1 | Ask the Lonely | Four Tops | 3:00 |
| 22.2 | Where Did You Go | Four Tops | 2:26 |
| 22.3 | Do You Know What I’m Talkin’ About | The Downbeats | 3:02 |
| 22.4 | You Say You Love Me | The Downbeats | 2:29 |
| 22.5 | Conscience I’m Guilty | Hattie Littles | 3:04 |
| 22.6 | You Got Me Worried | Hattie Littles | 2:58 |
| 22.7 | Shotgun | Junior Walker, Willie Woods | 2:58 |
| 22.8 | Hot Cha | Jr. Walker & the All Stars | 3:03 |
| 22.9 | All for You | Earl Van Dyke & The Soul Brothers | 2:58 |
| 22.10 | Too Many Fish in the Sea | Earl Van Dyke & The Soul Brothers | 2:19 |
| 22.11 | Love Makes the World Go ’round, but Money Greases the Wheel | Dee Mullins | 2:10 |
| 22.12 | Come on Back (and Be My Love Again) | Dee Mullins | 2:23 |
| 22.13 | I’m Still Loving You | Kim Weston | 2:49 |
| 22.14 | Go Ahead and Laugh (second version) | Kim Weston | 2:57 |
| 22.15 | Nowhere to Run | Martha and the Vandellas | 2:52 |
| 22.16 | Motoring | Martha and the Vandellas | 2:46 |
| 22.17 | Stop! In the Name of Love (promo version) | The Supremes | 2:55 |
| 22.18 | I’m in Love Again | The Supremes | 2:21 |
| 22.19 | Stop! In the Name of Love (commercial version) | Diana Ross, Florence Ballard, Mary Wilson, The Andantes | 2:53 |
| 22.20 | When I’m Gone | Brenda Holloway | 2:08 |
| 22.21 | I’ve Been Good to You | Brenda Holloway | 3:06 |
| 22.22 | When I’m Gone (second version) | Brenda Holloway | 2:11 |
| 22.23 | I’ll Be Doggone | Marvin Gaye | 2:53 |
| 22.24 | You’ve Been a Long Time Coming | Marvin Gaye | 2:15 |
| 22.25 | I’ll Be Doggone (second version) | Marvin Gaye | 2:51 |
| 22.26 | Ooo Baby Baby | The Miracles | 2:44 |
| 22.27 | All That’s Good | The Miracles | 2:55 |
| 22.28 | It’s Growing | David Ruffin, The Andantes | 2:58 |
| 22.29 | What Love Has Joined Together | Eddie Kendricks | 2:55 |
| 23.1 | Never Say No to Your Baby | The Hit Pack | 2:31 |
| 23.2 | Let’s Dance | The Hit Pack | 2:07 |
| 23.3 | Kiss Me Baby | Stevie Wonder | 2:13 |
| 23.4 | You Only Pass This Way One Time | The Hillsiders | 2:05 |
| 23.5 | Rain Is a Lonesome Thing | The Hillsiders | 2:36 |
| 23.6 | My Baby | The Freeman Brothers | 2:34 |
| 23.7 | Beautiful Brown Eyes | The Freeman Brothers | 2:30 |
| 23.8 | Back in My Arms Again (promo version) | The Supremes | 2:55 |
| 23.9 | Whisper You Love Me Boy | The Supremes | 2:40 |
| 23.10 | Back in My Arms Again (commercial version) | Diana Ross | 2:58 |
| 23.11 | A Thrill a Moment | Kim Weston | 3:01 |
| 23.12 | I’ll Never See My Love Again | Kim Weston | 2:55 |
| 23.13 | I Can’t Help Myself (Sugar Pie, Honey Bunch) | Four Tops | 2:44 |
| 23.14 | Sad Souvenirs | Four Tops | 2:41 |
| 23.15 | I Can’t Help Myself (Sugar Pie, Honey Bunch) (second version) | Four Tops | 2:46 |
| 23.16 | All the Good Times Are Gone | Howard Crockett | 3:01 |
| 23.17 | The Great Titanic | Howard Crockett | 2:43 |
| 23.18 | Lonely Lonely Girl Am I | The Velvelettes | 2:11 |
| 23.19 | I’m the Exception to the Rule | The Velvelettes | 2:20 |
| 23.20 | I’ll Keep on Holding On | The Marvelettes | 2:27 |
| 23.21 | No Time for Tears | The Marvelettes | 2:36 |
| 23.22 | Do the Boomerang | Jr. Walker & the All Stars | 2:21 |
| 23.23 | Tune Up | Jr. Walker & the All Stars | 3:05 |
| 23.24 | Operator | Brenda Holloway | 3:10 |
| 23.25 | I’ll Be Available | Brenda Holloway | 2:39 |
| 23.26 | Down to Earth | Billy Eckstine | 3:03 |
| 23.27 | Had You Been Around | Billy Eckstine | 2:45 |
| 24.1 | Buttered Popcorn | The Vows | 2:46 |
| 24.2 | Tell Me | The Vows | 2:38 |
| 24.3 | He’s an Oddball | The Lewis Sisters | 2:52 |
| 24.4 | By Some Chance | The Lewis Sisters | 3:00 |
| 24.5 | Why Do You Want to Let Me Go | Marv Johnson | 3:05 |
| 24.6 | I’m Not a Plaything | Marv Johnson | 2:09 |
| 24.7 | The Only Time I’m Happy | The Supremes | 2:30 |
| 24.8 | Supremes Interview | The Supremes | 5:42 |
| 24.9 | Since I Lost My Baby | David Ruffin | 2:52 |
| 24.10 | You’ve Got to Earn It | Eddie Kendricks | 2:39 |
| 24.11 | I’ll Always Love You | The Spinners | 2:46 |
| 24.12 | Tomorrow May Never Come | The Spinners | 2:30 |
| 24.13 | This Time Last Summer | Danny Day | 3:08 |
| 24.14 | Please Don’t Turn the Lights Out | Danny Day | 2:56 |
| 24.15 | Why Break My Heart (Just to Run Around) | Dorsey Burnette | 2:47 |
| 24.16 | They’re Only Words | Dorsey Burnette | 2:35 |
| 24.17 | Pretty Little Baby | Marvin Gaye | 2:37 |
| 24.18 | Now That You’ve Won Me | Marvin Gaye | 2:33 |
| 24.19 | First I Look at the Purse | The Contours | 3:04 |
| 24.20 | Searching for a Girl | The Contours | 2:49 |
| 24.21 | The Tracks of My Tears | The Miracles | 3:01 |
| 24.22 | A Fork in the Road | The Miracles | 3:20 |
| 24.23 | Shake and Fingerpop | Jr. Walker & the All Stars | 2:44 |
| 24.24 | Cleo’s Back | Jr. Walker & the All Stars | 2:31 |
| 24.25 | It’s the Same Old Song | Lawrence Payton, Levi Stubbs, Renaldo Benson, Abdul “Duke” Fakir, Louvain Demps, Jackie Hicks, Marlene Barrow | 2:47 |
| 24.26 | Your Love Is Amazing | Four Tops | 2:23 |
| 24.27 | It’s the Same Old Song (second version) | Four Tops | 2:44 |
| 25.1 | Mother Dear | The Supremes | 2:41 |
| 25.2 | Nothing but Heartaches | The Supremes | 2:42 |
| 25.3 | He Holds His Own | The Supremes | 2:31 |
| 25.4 | Nothing but Heartaches (second version) | The Supremes | 2:44 |
| 25.5 | Danger Heartbreak Dead Ahead | The Marvelettes | 2:24 |
| 25.6 | Your Cheating Ways | The Marvelettes | 2:58 |
| 25.7 | Your Cheating Ways (second version) | The Marvelettes | 2:54 |
| 25.8 | You’ve Changed Me | Brenda Holloway | 3:04 |
| 25.9 | Who’s Lovin’ You | Brenda Holloway | 2:44 |
| 25.10 | You’ve Been in Love Too Long | Martha and the Vandellas | 3:01 |
| 25.11 | Love (Makes Me Do Foolish Things) | Martha and the Vandellas | 2:55 |
| 25.12 | High Heel Sneakers | Stevie Wonder | 3:06 |
| 25.13 | Funny (How Time Slips Away) | Stevie Wonder | 3:50 |
| 25.14 | Music Talk | Stevie Wonder | 2:58 |
| 25.15 | The Bigger Your Heart Is (the Harder You’ll Fall) | Tony Martin | 2:40 |
| 25.16 | The Two of Us | Tony Martin | 2:31 |
| 25.17 | I Don’t Know What to Do | Richard Anthony | 2:00 |
| 25.18 | What Now My Love | Richard Anthony | 2:37 |
| 25.19 | Hang On Bill | Little Lisa | 2:51 |
| 25.20 | Puppet on a String | Little Lisa | 2:05 |
| 25.21 | You Can Cry on My Shoulder | Brenda Holloway | 2:50 |
| 25.22 | How Many Times Did You Mean It | Brenda Holloway | 3:01 |
| 25.23 | You Can Cry on My Shoulder (second version) | Brenda Holloway | 2:55 |
| 25.24 | You Need Me | The Lewis Sisters | 2:50 |
| 25.25 | Moonlight on the Beach | The Lewis Sisters | 2:50 |
| 25.26 | Take Me in Your Arms (Rock Me a Little While) | Kim Weston | 2:56 |
| 25.27 | Don’t Compare Me With Her | Kim Weston | 2:38 |
| 25.28 | Things Are Changing | The Supremes | 2:57 |
| 26.1 | Ain’t That Peculiar | Marvin Gaye | 2:51 |
| 26.2 | She’s Got to Be Real | Marvin Gaye | 2:53 |
| 26.3 | Ain’t That Peculiar (second version) | Marvin Gaye | 2:59 |
| 26.4 | My Girl Has Gone | The Miracles | 2:54 |
| 26.5 | Since You Won My Heart | The Miracles | 2:15 |
| 26.6 | My Girl Has Gone (second version) | The Miracles | 2:52 |
| 26.7 | My Baby | David Ruffin | 3:00 |
| 26.8 | Don’t Look Back | Paul Williams | 2:52 |
| 26.9 | My Baby (second version) | The Temptations | 2:58 |
| 26.10 | Don’t Look Back (second version) | The Temptations | 2:53 |
| 26.11 | I Can’t Help Myself (Sugar Pie, Honey Bunch) | Earl Van Dyke & The Soul Brothers | 2:44 |
| 26.12 | How Sweet It Is (to Be Loved by You) | Earl Van Dyke & The Soul Brothers | 2:51 |
| 26.13 | I Hear a Symphony | Diana Ross, Florence Ballard, Mary Wilson | 2:43 |
| 26.14 | Who Could Ever Doubt My Love | The Supremes | 2:37 |
| 26.15 | As Long as There Is L‐O‐V‐E Love | Jimmy Ruffin | 2:51 |
| 26.16 | How Can I Say I’m Sorry | Jimmy Ruffin | 2:33 |
| 26.17 | We Call It Fun | The Headliners | 2:14 |
| 26.18 | Voodoo Plan | The Headliners | 2:27 |
| 26.19 | Something About You | Four Tops | 2:50 |
| 26.20 | Darling, I Hum Our Song | Four Tops | 2:23 |
| 26.21 | I’ve Been Cheated | The Dalton Boys | 2:36 |
| 26.22 | Take My Hand | The Dalton Boys | 2:48 |
| 26.23 | Something’s Bothering You | The Dalton Boys | 2:59 |
| 26.24 | Let’s Go Somewhere | R. Dean Taylor | 2:52 |
| 26.25 | Say You | The Monitors | 2:33 |
| 26.26 | All for Someone | The Monitors | 2:18 |
| 26.27 | I Can’t Believe You Love Me | Tammi Terrell | 2:37 |
| 26.28 | Hold Me Oh My Darling | Tammi Terrell | 2:37 |
| 27.1 | You’re Gonna Love My Baby | Barbara McNair | 2:57 |
| 27.2 | The Touch of Time | Barbara McNair | 3:03 |
| 27.3 | Children’s Christmas Song | The Supremes | 2:47 |
| 27.4 | Twinkle Twinkle Little Me | The Supremes | 3:03 |
| 27.5 | Uptight (Everything’s Alright) | Stevie Wonder | 2:53 |
| 27.6 | Purple Rain Drops | Stevie Wonder | 3:09 |
| 27.7 | A Bird in the Hand (Is Worth Two in the Bush) | The Velvelettes | 2:52 |
| 27.8 | Since You’ve Been Loving Me | The Velvelettes | 2:15 |
| 27.9 | Don’t Mess With Bill | The Marvelettes | 2:50 |
| 27.10 | Anything You Wanna Do | The Marvelettes | 2:24 |
| 27.11 | The Flick, Part 2 | Earl Van Dyke & The Soul Brothers | 2:53 |
| 27.12 | The Flick, Part 1 | Earl Van Dyke & The Soul Brothers | 2:51 |
| 27.13 | Do Right Baby Do Right | Chris Clark | 2:57 |
| 27.14 | Don’t Be Too Long | Chris Clark | 2:35 |
| 27.15 | Do Right Baby Do Right (second version) | Chris Clark | 2:51 |
| 27.16 | Going to a Go‐Go | The Miracles | 2:50 |
| 27.17 | Choosey Beggar | The Miracles | 2:33 |
| 27.18 | Ask Any Man | Tony Martin | 2:40 |
| 27.19 | Spanish Rose | Tony Martin | 2:48 |
| 27.20 | Cleo’s Mood | Jr. Walker & the All Stars | 2:41 |
| 27.21 | Baby You Know You Ain’t Right | Jr. Walker & the All Stars | 2:32 |
| 27.22 | My World Is Empty Without You | The Supremes | 2:36 |
| 27.23 | Everything Is Good About You | The Supremes | 3:12 |
| 27.24 | Do I Love You (Indeed I Do) | Frank Wilson | 2:33 |
| 27.25 | Sweeter as the Days Go By | Frank Wilson | 2:52 |
| 27.26 | Put Yourself in My Place | The Elgins | 2:28 |
| 27.27 | Darling Baby | The Elgins | 2:36 |