| 1.1 | Opening Medley: When the Lovelight Starts Shining Through His Eyes / Come See About Me / Stop! In the Name of Love / Love Is Like an Itching in My Heart / You Keep Me Hangin’ On | Diana Ross & The Supremes and The Temptations | 3:18 |
| 1.2 | Try It Baby | Melvin Franklin | 3:45 |
| 1.3 | I Second That Emotion (extended) | Eddie Kendricks | 2:32 |
| 1.4 | Ain’t No Mountain High Enough | Diana Ross & The Supremes and The Temptations | 2:19 |
| 1.5 | I’m Gonna Make You Love Me | Diana Ross, Eddie Kendricks, Otis Williams | 3:08 |
| 1.6 | This Guy’s in Love With You | Diana Ross & The Supremes and The Temptations | 3:45 |
| 1.7 | Funky Broadway | Diana Ross & The Supremes and The Temptations | 2:37 |
| 1.8 | I’ll Try Something New | Eddie Kendricks | 2:21 |
| 1.9 | A Place in the Sun | Diana Ross & The Supremes and The Temptations | 3:31 |
| 1.10 | Sweet Inspiration | Diana Ross & The Supremes and The Temptations | 2:57 |
| 1.11 | Then (extended) | Diana Ross & The Supremes and The Temptations | 2:20 |
| 1.12 | The Impossible Dream | Diana Ross & The Supremes and The Temptations | 4:52 |
| 1.13 | Medley: You Can’t Hurry Love / You Keep Me Hangin’ On | Diana Ross & The Supremes and The Temptations | 2:40 |
| 1.14 | Got to Get You Into My Life | Diana Ross & The Supremes and The Temptations | 2:43 |
| 1.15 | You Gave Me Something (and Everything’s Alright) | Diana Ross & The Supremes and The Temptations | 2:50 |
| 1.16 | A House Is Not a Home | Diana Ross & The Supremes and The Temptations | 3:21 |
| 1.17 | If You Should Walk Away | Diana Ross & The Supremes | 3:11 |
| 1.18 | Amen | Diana Ross & The Supremes and The Temptations | 2:17 |
| 2.1 | Stubborn Kind of Fellow | Diana Ross & The Supremes and The Temptations | 3:10 |
| 2.2 | I’ll Be Doggone | Paul Williams | 3:35 |
| 2.3 | The Weight | Diana Ross, Eddie Kendricks, Paul Williams | 3:04 |
| 2.4 | Ain’t Nothing Like the Real Thing | Dennis Edwards | 2:47 |
| 2.5 | Uptight (Everything’s Alright) | Diana Ross & The Supremes and The Temptations | 3:06 |
| 2.6 | Sing a Simple Song | Mary Wilson | 3:34 |
| 2.7 | My Guy, My Girl | Diana Ross & The Supremes and The Temptations | 3:16 |
| 2.8 | For Better or Worse | Diana Ross & The Supremes and The Temptations | 2:38 |
| 2.9 | Can’t Take My Eyes Off You | Mary Wilson | 3:13 |
| 2.10 | Why (Must We Fall in Love) (extended) | Diana Ross & The Supremes and The Temptations | 3:14 |
| 2.11 | I’ll Try Something New (single mix) | Eddie Kendricks | 2:26 |
| 2.12 | Stubborn Kind of Fellow (single mix) | Diana Ross & The Supremes and The Temptations | 3:49 |
| 2.13 | Try It Baby (single mix) | Melvin Franklin | 3:07 |
| 2.14 | Funky Broadway (mono mix) | Diana Ross & The Supremes and The Temptations | 2:44 |
| 2.15 | The Weight (mono mix) | Eddie Kendricks, Paul Williams | 2:53 |
| 2.16 | Sing a Simple Song (mono mix) | Mary Wilson | 3:39 |
| 2.17 | My Guy, My Girl (mono mix) | Diana Ross & The Supremes and The Temptations | 3:23 |
| 2.18 | Can’t Take My Eyes Off You (Mary Wilson solo version) | Mary Wilson | 3:14 |
| 2.19 | I’m Gonna Make You Love Me (alternate mix with spoken intro) | Diana Ross, Eddie Kendricks, Otis Williams | 3:15 |
| 2.20 | Not Now, I’ll Tell You Later (extended alternate mix) | The Temptations with The Supremes | 3:40 |