| 1.1 | Les Pêcheurs de perles: « Au fond du temple saint » | David Hobson, Teddy Tahu Rhodes | 5:43 |
| 1.2 | Nabucco: “Va, pensiero” | Opera Australia Chorus | 4:53 |
| 1.3 | Lakmé: « Sous le dôme épais » | Glenys Fowles, Heather Begg | 5:14 |
| 1.4 | Così fan tutte: “Soave sia il vento” | Amanda Thane, Fiona Janes, David Brennan | 2:38 |
| 1.5 | Dido and Aeneas: “Thy hand, Belinda” | Fiona Campbell | 4:56 |
| 1.6 | Madama Butterfly: “Un bel dì” | Cheryl Barker | 4:26 |
| 1.7 | Tristan und Isolde: Liebestod | Marilyn Richardson | 6:23 |
| 1.8 | Rigoletto: “Un dì, si ben rammentomi” | Luciano Pavarotti, Joan Sutherland, Sherrill Milnes, Huguette Tourangeau | 5:31 |
| 1.9 | Orfeo ed Euridice: “Che faro senza Euridice” | Lauris Elms | 3:53 |
| 1.10 | Der Rosenkavalier: “Marie Theres’… Ist ein Traum” | Helen Donath, Yvonne Minton, Régine Crespin, Otto Wiener | 12:45 |
| 1.11 | Rusalka: Song to the Moon | Yvonne Kenny | 6:21 |
| 1.12 | Turandot: “Nessun dorma” | Luciano Pavarotti, The John Alldis Choir | 2:59 |
| 2.1 | Norma: “Casta diva” | Joan Sutherland, Clifford Grant, Opera Australia Chorus | 6:17 |
| 2.2 | La Bohème: “O soave fanciulla“ | David Hobson, Cheryl Barker | 4:13 |
| 2.3 | La Bohème: “Che gelida manina” | David Hobson | 4:39 |
| 2.4 | Madama Butterfly: “Vogliatemi bene” (Act 1 Love Duet) | Cheryl Barker, Jay Hunter Morris | 7:36 |
| 2.5 | Lucia di Lammermoor: “Eccola! Il dolce suono“ (Act 3 Mad Scene) | Joan Sutherland, Opera Australia Chorus, Robin Donald | 20:14 |
| 2.6 | The Magic Flute: “Der Hölle Rache…” (Queen of the night aria) | Cyndia Sieden | 3:03 |
| 2.7 | Madama Butterfly: The Humming Chorus | Chor der Wiener Staatsoper | 3:04 |
| 2.8 | Gianni Schicchi: “O mio babbino caro“ | Yvonne Kenny | 2:27 |
| 2.9 | Faust : “Alerte ! Alerte ! Anges purs“ | Joan Sutherland, Ambrosian Singers, Nicolaï Ghiaurov, Franco Corelli | 5:26 |
| 2.10 | Tosca: “E lucevan le stelle” | Franco Corelli | 3:15 |
| 2.11 | Cavalleria rusticana: Intermezzo | Pietro Mascagni | 3:08 |
| 2.12 | Fidelio: “Mir ist so wunderbar” (Act 1 quartet) | Hildegard Behrens, David Kuebler, Hans Sotin, Sona Ghazarian | 5:15 |
| 3.1 | Carmen : « L’Amour est un oiseau rebelle » | Lauris Elms | 3:44 |
| 3.2 | Don Giovanni: Atto II. “Don Giovanni, a cenar teco” | Bryn Terfel, London Voices, Michele Pertusi, Mario Luperi | 6:10 |
| 3.3 | Samson et Dalila : Acte II. « Mon cœur s’ouvre à ta voix » | Lauris Elms | 5:36 |
| 3.4 | Aida: Gloria all’Egitto | Coro del Teatro alla Scala di Milano | 9:33 |
| 3.5 | Le nozze di Figaro: Atto IV. “Pace, pace” | Elisabeth Schwarzkopf, Erich Kunz, George London, Erich Majkut, Irmgard Seefried, Chorus of the Vienna State Opera, Wilhelm Felden, Marjan Rus | 7:11 |
| 3.6 | La Wally: “Ebben?” | Yvonne Kenny | 4:02 |
| 3.7 | Lucia di Lammermoor: Atto II. “Chi mi frena” | Joan Sutherland, Clifford Grant, Patricia Price, Richard Greager, Sergei Baigildin, Malcolm Donnelly, Opera Australia Chorus | 4:00 |
| 3.8 | Tosca: Atto II. “Vissi d’arte” | Rita Hunter | 3:17 |
| 3.9 | Tosca: Atto I. “Tre sbirri, una carrozza” | Coro del Teatro alla Scala di Milano, Tito Gobbi, Angelo Mercuriali | 4:27 |
| 3.10 | Le nozze di Figaro: Atto III. “Dove sono i bei momenti” | Isobel Buchanan | 4:33 |
| 3.11 | Der Rosenkavalier: “Mir ist die Ehre widerfahren” | Barbara Bonney, Susan Graham | 7:18 |
| 3.12 | Don Giovanni: “Là ci darem la mano” | Isobel Buchanan, John Pringle | 3:08 |
| 3.13 | Cavalleria rusticana: Easter Hymn | London Opera Chorus, Júlia Várady | 5:24 |
| 4.1 | Rinaldo: “Lascia ch’io pianga” | Yvonne Kenny | 4:20 |
| 4.2 | The Magic Flute: “Pa‐pa‐pa‐Papagena” | Isobel Buchanan, John Pringle | 2:29 |
| 4.3 | Die Walküre: “Leb wohl” (Wotan’s Farewell) | John Wegner | 9:02 |
| 4.4 | Pagliacci: “Recitar! … "Vesti la giubba”" | Jussi Björling | 3:51 |
| 4.5 | Tannhäuser: “Beglückt darf nun dich” (Pilgrim’s Chorus) | Helga Dernesch, Victor Braun, Chor der Wiener Staatsoper | 4:50 |
| 4.6 | Hänsel und Gretel: “Abends, will ich schlafen gehn” (Evening Prayer) … Dream Pantomime | Elisabeth Schwarzkopf, Elisabeth Grümmer | 9:31 |
| 4.7 | Beatrice di Tenda: “Angiol di pace” | Joan Sutherland, Marilyn Horne, Richard Conrad | 3:26 |
| 4.8 | Die tote Stadt: “Glück, das mir verblieb” (Marietta’s Song) | Joan Hammond | 4:29 |
| 4.9 | Les Pêcheurs de perles: « Je crois entendre encore » | David Hobson | 3:38 |
| 4.10 | Serse: “Ombra mai fù” | Andreas Scholl | 2:59 |
| 4.11 | La traviata: “Libiamo, ne’ lieti calici” | Luciano Pavarotti, Joan Sutherland | 3:09 |
| 4.12 | Madama Butterfly: “Tu, tu piccolo Iddio” | Renata Tebaldi | 4:36 |
| 4.13 | Le nozze di Figaro: “Voi che sapete” | Elisabeth Schwarzkopf | 2:58 |