| 1.1 | Stubborn Kind of Fellow | Marvin Gaye, Martha Reeves, Rosalind Ashford, Annette Beard, Gloria Williams | 2:45 |
| 1.2 | Pride and Joy | Marvin Gaye | 2:07 |
| 1.3 | Hitch Hike | Marvin Gaye, Martha Reeves, Rosalind Ashford, Annette Beard | 2:33 |
| 1.4 | Wherever I Lay My Hat (That’s My Home) | Marvin Gaye | 2:15 |
| 1.5 | What Do You Want With Him | Marvin Gaye | 2:37 |
| 1.6 | Once Upon a Time | Mary Wells | 2:32 |
| 1.7 | What’s the Matter With You Baby | Mary Wells | 2:23 |
| 1.8 | Can I Get a Witness | Marvin Gaye | 2:48 |
| 1.9 | Couldn’t Ask for More | Marvin Gaye | 2:42 |
| 1.10 | You’re Wonderful | Marvin Gaye | 2:45 |
| 1.11 | I Wonder | Marvin Gaye | 3:44 |
| 1.12 | You’re a Wonderful One | Marvin Gaye | 2:45 |
| 1.13 | It’s Got to Be Love | Marvin Gaye | 2:39 |
| 1.14 | Try It Baby | Marvin Gaye | 3:00 |
| 1.15 | Leavin’ | Marvin Gaye | 2:22 |
| 1.16 | My Love for You | Marvin Gaye | 3:00 |
| 1.17 | How Sweet It Is (to Be Loved by You) | Marvin Gaye | 2:59 |
| 1.18 | Baby Don’t You Do It | Marvin Gaye | 2:33 |
| 1.19 | Just Like a Man | Marvin Gaye | 2:50 |
| 1.20 | Pretty Little Baby | Marvin Gaye | 2:36 |
| 1.21 | Talk About a Good Feeling | Marvin Gaye | 2:24 |
| 1.22 | I’ll Be Doggone | Marvin Gaye | 2:51 |
| 1.23 | Little Darling (I Need You) | Marvin Gaye | 2:46 |
| 1.24 | One More Heartache | Marvin Gaye | 2:34 |
| 1.25 | Ain’t That Peculiar | Marvin Gaye | 2:59 |
| 1.26 | You’re the One for Me | Marvin Gaye | 3:42 |
| 1.27 | Take This Heart of Mine | Marvin Gaye | 2:44 |
| 1.28 | Your Unchanging Love | Marvin Gaye | 3:03 |
| 2.1 | It Takes Two | Kim Weston | 2:58 |
| 2.2 | I Couldn’t Help Falling for You | Marvin Gaye & Kim Weston | 2:55 |
| 2.3 | Lonely Lover (alternate mix) | Marvin Gaye | 2:25 |
| 2.4 | Without Your Sweet Lovin’ | Marvin Gaye | 2:30 |
| 2.5 | Ain’t No Mountain High Enough | Marvin Gaye & Tammi Terrell | 2:28 |
| 2.6 | If I Could Build My Whole World Around You | Tammi Terrell | 2:22 |
| 2.7 | Your Precious Love | Tammi Terrell | 3:00 |
| 2.8 | If This World Were Mine | Marvin Gaye & Tammi Terrell | 2:43 |
| 2.9 | Without You (My World Is Lonely) | Marvin Gaye | 2:41 |
| 2.10 | Together We Stand (Divided We Fall) | Marvin Gaye | 2:52 |
| 2.11 | You | Marvin Gaye | 2:26 |
| 2.12 | Chained | Marvin Gaye | 2:36 |
| 2.13 | I Heard It Through the Grapevine | Marvin Gaye, The Andantes, Louvain Demps, Jackie Hicks, Marlene Barrow | 3:14 |
| 2.14 | You’re What’s Happening (In the World Today) | Marvin Gaye | 2:20 |
| 2.15 | This Love Starved Heart of Mine (It’s Killing Me) | Marvin Gaye | 2:42 |
| 2.16 | Ain’t Nothing Like the Real Thing | Marvin Gaye, Tammi Terrell, Valerie Simpson, Nickolas Ashford | 2:17 |
| 2.17 | Keep On Lovin’ Me Honey | Marvin Gaye & Tammi Terrell | 2:30 |
| 2.18 | You’re All I Need to Get By | Marvin Gaye & Tammi Terrell | 2:40 |
| 2.19 | Too Busy Thinking About My Baby | Marvin Gaye | 2:57 |
| 2.20 | More Than a Heart Can Stand | Marvin Gaye | 2:56 |
| 2.21 | How Can I Forget | Marvin Gaye | 2:04 |
| 2.22 | That’s the Way Love Is | Marvin Gaye | 3:37 |
| 2.23 | Yesterday | Marvin Gaye | 3:25 |
| 2.24 | The End of Our Road | Marvin Gaye | 2:46 |
| 2.25 | Good Lovin’ Ain’t Easy to Come By | Marvin Gaye & Tammi Terrell | 2:19 |
| 2.26 | What You Gave Me | Marvin Gaye & Tammi Terrell | 2:37 |
| 3.1 | What’s Going On | Marvin Gaye, Mel Farr, Lem Barney | 3:53 |
| 3.2 | Save the Children | Marvin Gaye | 4:02 |
| 3.3 | Mercy Mercy Me (The Ecology) | Marvin Gaye, The Andantes | 3:16 |
| 3.4 | Inner City Blues (Make Me Wanna Holler) | Marvin Gaye | 5:29 |
| 3.5 | I’m Going Home (alternative mix) | Marvin Gaye | 4:39 |
| 3.6 | Piece of Clay | Marvin Gaye | 5:11 |
| 3.7 | You’re the Man, Parts I & II | Marvin Gaye | 5:46 |
| 3.8 | Checking Out (Double Clutch) | Marvin Gaye | 4:53 |
| 3.9 | Trouble Man | Marvin Gaye | 4:55 |
| 3.10 | Let’s Get It On | Marvin Gaye | 4:53 |
| 3.11 | Come Get to This | Marvin Gaye | 2:41 |
| 3.12 | Just to Keep You Satisfied | Marvin Gaye, The Originals | 4:27 |
| 3.13 | Pledging My Love | Diana Ross & Marvin Gaye | 3:35 |
| 3.14 | My Mistake (Was to Love You) | Diana Ross & Marvin Gaye | 2:55 |
| 3.15 | Distant Lover (live) | Marvin Gaye | 6:22 |
| 3.16 | I Want You | Marvin Gaye | 4:34 |
| 3.17 | After the Dance | Marvin Gaye | 5:11 |
| 3.18 | [silence] | Marvin Gaye | |
| 4.1 | Got to Give It Up, Part I | Marvin Gaye | 4:14 |
| 4.2 | Here, My Dear | Marvin Gaye | 2:49 |
| 4.3 | When Did You Stop Loving Me, When Did I Stop Loving You | Marvin Gaye | 6:16 |
| 4.4 | Anger | Marvin Gaye | 4:02 |
| 4.5 | Anna’s Song | Marvin Gaye | 5:55 |
| 4.6 | A Funky Space Reincarnation | Marvin Gaye | 8:18 |
| 4.7 | When Did You Stop Loving Me, When Did I Stop Loving You (reprise) | Marvin Gaye | 0:45 |
| 4.8 | She Needs Me | Marvin Gaye | 3:31 |
| 4.9 | Why Did I Choose You | Marvin Gaye | 2:37 |
| 4.10 | Life Is for Learning | Marvin Gaye | 3:40 |
| 4.11 | Funk Me | Marvin Gaye | 5:35 |
| 4.12 | Love Me Now or Love Me Later | Marvin Gaye | 5:00 |
| 4.13 | Ego Tripping Out | Marvin Gaye | 5:13 |
| 4.14 | The Star Spangled Banner | Marvin Gaye | 3:14 |
| 4.15 | I Heard It Through the Grapevine | Marvin Gaye feat. Gladys Knight | 3:48 |
| 4.16 | Rockin’ After Midnight | Marvin Gaye | 6:05 |
| 4.17 | Sexual Healing | Marvin Gaye, Harvey Fuqua, Gordon Banks | 4:04 |
| 4.18 | The Lord’s Prayer | Marvin Gaye | 1:55 |