“Death of a Spy”, Opening Titles

On these albums

Doctor Who: The Myth MakersDonald Cotton starring William Hartnell, Maureen O’Brien & Peter Purves · 2001Soundtrack

Doctor Who: Adventures in HistoryWilliam Hartnell, Patrick Troughton with linking narration by Peter Purves & Frazer Hines · 2003Soundtrack

Doctor Who: The Lost TV Episodes - Collection OneVarious Artists · 2010

Source: MusicBrainz recording 0cd6e2d5-15b7-49b9-9da3-d20a2c8b2bca (CC0).